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arxiv: physics/0601152 · v1 · submitted 2006-01-20 · ⚛️ physics.atom-ph · physics.chem-ph

Calculation of ground- and excited-state energies of confined helium atom

classification ⚛️ physics.atom-ph physics.chem-ph
keywords energiesvariationalatomcalculationconfinedexcitedgroundhelium
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We calculate the energies of ground and three low lying excited states of confined helium atom centered in an impenetrable spherical box. We perform the calculation by employing variational method with two-parameter variational forms for the correlated two-particle wave function. With just two variational parameters we get quite accurate results for both ground and excited state energies.

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