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pith:2026:FZHWMBQ4ZHZUVSRTLRSVM4J574
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Multiscale morphology and contact mechanics of physisorbed Al and Cu nanoparticles

Mykola Prodanov, Oleksii Khomenko

Al and Cu nanoparticles smaller than 3-6 nm on graphene show non-standard scaling and rapid contact changes

arxiv:2604.07646 v1 · 2026-04-08 · cond-mat.mes-hall · cond-mat.soft

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Claims

C1strongest claim

NPs with a surface area-to-volume ratio above about 1.8 nm^{-1}, or with a linear size under 3-6 nm, behave differently from larger particles. For these smaller NPs, scaling of their total surface area and volume with the linear size can deviate from quadratic and cubic dependencies, respectively. Their mean interfacial separation and relative contact area change rapidly with size.

C2weakest assumption

The molecular dynamics model and the procedure mimicking thermal dewetting of thin films accurately capture the physisorption interactions and morphological evolution of real Al and Cu nanoparticles on suspended graphene without significant artifacts from potentials or finite-size effects.

C3one line summary

Small Al and Cu nanoparticles on graphene show deviations from quadratic and cubic scaling in surface and volume, rapid changes in contact properties, and irregular height distributions below 3-6 nm, while larger ones exhibit Gaussian fits and self-affine roughness.

References

17 extracted · 17 resolved · 1 Pith anchors

[1] Multiscale morphology and contact mechanics of physisorbed Al and Cu nanoparticles 2026 · arXiv:2604.07646
[2] 22 for an example ofP tot (u)for a NP with 681472 atoms 2000
[3] The size scaling ofA r in Figs. 32, 33 is consistent with the reported¯udependence: smaller NPs have a lowerA r reflecting larger¯u. This means that, geometrically , water molecules are harder to leak 2008
[4] 3 K. S. Suhas, V. K. Reddy , T. Reddy and Y. Pai,Discover Materi- als, 2026,6, 2026
[5] 4 S. Harsha, R. K. Sharma, M. Dierner, C. Baeumer, I. Makhotkin, G. Mul, P. Ghigna, E. Spiecker, J. Will and M. Al- tomare,Advanced Functional Materials, 2024,34, 2403628. 5 M. Kim, H.-J. Ahn, V. C. S 2024

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First computed 2026-05-20T02:05:43.129972Z
Builder pith-number-builder-2026-05-17-v1
Signature Pith Ed25519 (pith-v1-2026-05) · public key
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2e4f66061cc9f34aca335c6556713dff254fea0b43a8c330349065da720a808e

Aliases

arxiv: 2604.07646 · arxiv_version: 2604.07646v1 · doi: 10.48550/arxiv.2604.07646 · pith_short_12: FZHWMBQ4ZHZU · pith_short_16: FZHWMBQ4ZHZUVSRT · pith_short_8: FZHWMBQ4
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curl -sH 'Accept: application/ld+json' https://pith.science/pith/FZHWMBQ4ZHZUVSRTLRSVM4J574 \
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Canonical record JSON
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