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pith:2026:JLYKATINIQVB4AJWEGTSW2Q3PI
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Field-Induced Ferroelectric Phase Transition Dynamics in PMN-PT compositions near the Morphotropic Phase Boundary

Eduard Illin, Eugene V. Colla, Joseph Kerchenfaut, Shivjeet Chanan

PMN-PT near the morphotropic phase boundary remembers prior electric-field exposure to accelerate ferroelectric ordering.

arxiv:2601.21055 v2 · 2026-01-28 · cond-mat.mtrl-sci · cond-mat.dis-nn

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Claims

C1strongest claim

PMN-PT compositions near the MPB exhibit phase-transition dynamics that differ markedly from those far below the MPB. Electric-field history significantly affects the field-induced transition temperature Tc, zero-field-cooling delay time tau_ZFC, and induced polarization Pc; under specific conditions the material retains a memory of its electric-field history and uses it to kinetically accelerate ferroelectric ordering.

C2weakest assumption

That the marked differences in dynamics and the memory effect are caused primarily by proximity to the MPB rather than by uncontrolled variations in sample quality, electrode interfaces, or the specific field protocols chosen.

C3one line summary

PMN-PT near the MPB shows field-history-dependent phase transition dynamics, including memory effects that accelerate ferroelectric ordering under specific conditions.

References

31 extracted · 31 resolved · 0 Pith anchors

[1] H. Wu and R. Cohen, Electric-field-induced phase tran- sition and electrocaloric effect in pmn-pt, Phys. Rev. B 96, 054116 (2017) 2017
[2] B. Noheda, D. Cox, G. Shirane, J. Gao, and Z.- G. Ye, Phase diagram of the ferroelectric relaxor (1- x)PbMg1/3N2/3O3-(x)PbTiO3, Phys. Rev. B66, 054104 (2002) 2002
[3] M. Ahart, S. Stanislav, O. Shebanova, D. Ikuta, Z.-G. Ye, H. Mao, R. Cohen, and R. J. Hemley, Pressure depen- dence of the monoclinic phase in (1-x)PbMg 1/3Nb2/3O3- (x)PbTiO3, Phys. Rev. B86, 224111 ( 2012
[4] I.-H. Kim, I.-H. Kim, S.-G. Im, and K.-O. Jang, A phenomenological study on temperature-concentration- electric field phase diagram of relaxor ferroelectrics pmn- pt single crystals, Physica B Condens 2022
[5] M. Davis, D. Damjanovic, and N. Setter, Electric-field- , temperature-, and stress-induced phase transitions in relaxor ferroelectric single crystals, Phys. Rev. B73, 014115 (2006) 2006
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First computed 2026-06-02T03:04:37.315245Z
Builder pith-number-builder-2026-05-17-v1
Signature Pith Ed25519 (pith-v1-2026-05) · public key
Schema pith-number/v1.0

Canonical hash

4af0a04d0d442a1e013621a72b6a1b7a20d54e294ea612e33dc03d3b6faa80d6

Aliases

arxiv: 2601.21055 · arxiv_version: 2601.21055v2 · doi: 10.48550/arxiv.2601.21055 · pith_short_12: JLYKATINIQVB · pith_short_16: JLYKATINIQVB4AJW · pith_short_8: JLYKATIN
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curl -sH 'Accept: application/ld+json' https://pith.science/pith/JLYKATINIQVB4AJWEGTSW2Q3PI \
  | jq -c '.canonical_record' \
  | python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: 4af0a04d0d442a1e013621a72b6a1b7a20d54e294ea612e33dc03d3b6faa80d6
Canonical record JSON
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    "submitted_at": "2026-01-28T21:22:43Z",
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