Native-resolution retrievals on 0.97-5.27 micron JWST spectra of VHS 1256 b find a ~79% cloud deck, solar-like metallicity and C/O, and depleted 18O in a partially cloudy disequilibrium atmosphere.
Atmospheric Chemistry in Giant Planets, Brown Dwarfs, and Low-Mass Dwarf Stars III. Iron, Magnesium, and Silicon
5 Pith papers cite this work. Polarity classification is still indexing.
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abstract
We use thermochemical equilibrium calculations to model iron, magnesium, and silicon chemistry in the atmospheres of giant planets, brown dwarfs, extrasolar giant planets (EGPs), and low-mass stars. The behavior of individual Fe-, Mg-, and Si-bearing gases and condensates is determined as a function of temperature, pressure, and metallicity. Our results are thus independent of any particular model atmosphere. The condensation of Fe metal strongly affects iron chemistry by efficiently removing Fe-bearing species from the gas phase. Monatomic Fe is the most abundant Fe-bearing gas throughout the atmospheres of EGPs and L dwarfs and in the deep atmospheres of giant planets and T dwarfs. Mg- and Si-bearing gases are effectively removed from the atmosphere by forsterite (Mg2SiO4) and enstatite (MgSiO3) cloud formation. Monatomic Mg is the dominant magnesium gas throughout the atmospheres of EGPs and L dwarfs and in the deep atmospheres of giant planets and T dwarfs. Silicon monoxide (SiO) is the most abundant Si-bearing gas in the deep atmospheres of brown dwarfs and EGPs, whereas SiH4 is dominant in the deep atmosphere of Jupiter and other gas giant planets. Several other Fe-, Mg-, and Si-bearing gases become increasingly important with decreasing effective temperature. In principle, a number of Fe, Mg, and Si gases are potential tracers of weather or diagnostic of temperature in substellar atmospheres.
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Phase-resolved high-resolution spectroscopy of CoRoT-2b measures sub-synchronous rotation at 2.6-sigma significance, consistent with its western hotspot offset.
High-resolution M-band spectroscopy detects super-stellar SiO in TWA 5 B, implying no significant magnesium-silicate clouds and formation consistent with core accretion beyond the CO snowline or gravitational instability with solid enrichment.
Panchromatic JWST spectrum of WASP-121 b detects SiO and measures refractory-to-volatile ratios 3x stellar, consistent with mixed solid-gas accretion or migration with continued solid accretion.
Retrievals on six isolated brown dwarfs yield near-solar C/O (0.51-0.63), metallicities, and 12C/13C ratios (91-155) supporting molecular cloud fragmentation origin.
citing papers explorer
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Native-resolution retrievals of VHS 1256-1257 b spanning the JWST/NIRSpec wavelength range: Chemical composition of a partially cloudy atmosphere
Native-resolution retrievals on 0.97-5.27 micron JWST spectra of VHS 1256 b find a ~79% cloud deck, solar-like metallicity and C/O, and depleted 18O in a partially cloudy disequilibrium atmosphere.
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Unraveling the Mystery of the Peculiar and Young Hot Jupiter CoRoT-2b II: Phase Resolved Emission Spectroscopy with VLT/CRIRES+ and Gemini-S/IGRINS
Phase-resolved high-resolution spectroscopy of CoRoT-2b measures sub-synchronous rotation at 2.6-sigma significance, consistent with its western hotspot offset.
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The CRIMSON survey I: super-stellar SiO in the directly imaged companion TWA 5 B from high-resolution M-band spectroscopy
High-resolution M-band spectroscopy detects super-stellar SiO in TWA 5 B, implying no significant magnesium-silicate clouds and formation consistent with core accretion beyond the CO snowline or gravitational instability with solid enrichment.
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The panchromatic JWST dayside spectrum of WASP-121 b reveals a refractory-rich formation
Panchromatic JWST spectrum of WASP-121 b detects SiO and measures refractory-to-volatile ratios 3x stellar, consistent with mixed solid-gas accretion or migration with continued solid accretion.
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The ESO SupJup Survey XI. Atmospheric properties of six isolated M- and L-type dwarfs with CRIRES+
Retrievals on six isolated brown dwarfs yield near-solar C/O (0.51-0.63), metallicities, and 12C/13C ratios (91-155) supporting molecular cloud fragmentation origin.