A kinetic master equation model based on a nucleation-zipper pathway reproduces experimental shear rupture data for short dsDNA and shows that helical geometry is required to define end-to-end distance in the rod-like polymer model.
Macromolecules , Year =
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Knotting probability in polymer films maximizes at thicknesses near the bulk radius of gyration, vanishes for thin films, and can be reconstructed from layer properties in thick films.
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Polymer Knots in Thin Films: Thickness Dependence, Local Effects, and Stiffness
Knotting probability in polymer films maximizes at thicknesses near the bulk radius of gyration, vanishes for thin films, and can be reconstructed from layer properties in thick films.