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arxiv: 0707.3802 · v1 · submitted 2007-07-25 · ❄️ cond-mat.stat-mech · cond-mat.soft

Inconsistency of the non-standard definition of work

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords definitionnon-standardworkarbitraryarxivchangescond-matdepend
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We show that the recently postulated non-standard definition of work proportional to force variation rather than to displacement [A. Imparato and L. Peliti, cond-mat arXiv:0706.1134v1] is thermodynamically inconsistent at both microscopic and macroscopic scales and leads to non-physical results, including free energy changes that depend on arbitrary parameters.

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