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arxiv: 0803.2033 · v1 · submitted 2008-03-13 · ❄️ cond-mat.soft · cond-mat.stat-mech

A fundamental-measure density functional for mixtures of parallel hard cylinders

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords functionaldensityhardmixturescylindersparallelappliedfundamental
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We obtain a fundamental measure density functional for mixtures of parallel hard cylinders. To this purpose we first generalize to multicomponent mixtures the fundamental measure functional proposed by Tarazona and Rosenfeld for a one-component hard disk fluid, through a method alternative to the cavity formalism of these authors. We show the equivalence of both methods when applied to two-dimensional fluids. The density functional so obtained reduces to the exact density functional for one-dimensional mixtures of hard rods when applied to one-dimensional profiles. In a second step we apply an idea put forward some time ago by two of us, based again on a dimensional reduction of the system, and derive a density functional for mixtures of parallel hard cylinders. We explore some features of this functional by determining the fluid-fluid demixing spinodals for a binary mixture of cylinders with the same volume, and by calculating the direct correlation functions.

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