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Observation of Above-Threshold Dissociation of Na$_2^+$ in Intense Laser Fields

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arxiv 0806.2762 v5 pith:JJBM3V7H submitted 2008-06-17 physics.chem-ph physics.atm-clus

classification physics.chem-phphysics.atm-clus
keywords above-thresholddissociationcontinuum-continuummolecularobservationtransitionsassociatedbeen
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abstract

We report the observation of above-threshold dissociation of a multielectron molecular system, Na$_2^+$. The process is due to continuum-continuum transitions in a field-dressed molecular continuum. Three well resolved fragmentation channels with different kinetic energy release patterns have been detected, of which, two are associated with ordinary photodissociation via light-induced potentials into Na(3s) + Na$^+$ and Na(3p) + Na$^+$, and one with continuum-continuum transitions and above-threshold dissociation into Na(3p) + Na$^+$. We show that when we dress this molecule with a field whose intensity is ~3 x 10$^{12}$ W/cm$^2$, above-threshold dissociation prevails over other processes, such as field-ionization followed by Coulomb explosion.

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