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arxiv: 0811.0090 · v1 · pith:NRE2ET4Xnew · submitted 2008-11-03 · ❄️ cond-mat.stat-mech · physics.chem-ph· q-bio.PE

Switching rates of multi-step reactions

classification ❄️ cond-mat.stat-mech physics.chem-phq-bio.PE
keywords ratereactionsswitchingapproximationarbitraryconsidercontrolledemploying
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We consider a switching rate of a meta-stable reaction scheme, which includes reactions with arbitrary steps, e.g. $kA\to(k+r)A$. Employing WKB approximation, controlled by a large system size, we evaluate both the exponent and the pre-exponential factor for the rate. The results are illustrated on a number of examples.

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