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arxiv: 1006.1750 · v2 · pith:O2QDMIZLnew · submitted 2010-06-09 · ❄️ cond-mat.soft · cond-mat.stat-mech

A discrete model of water with two distinct glassy phases

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords modelwaterglassylatticephasesaccountanomaliesbreaking
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We investigate a minimal model for non-crystalline water, defined on a Husimi lattice. The peculiar random-regular nature of the lattice is meant to account for the formation of a random 4-coordinated hydrogen-bond network. The model turns out to be consistent with most thermodynamic anomalies observed in liquid and supercooled-liquid water. Furthermore, the model exhibits two glassy phases with different densities, which can coexist at a first-order transition. The onset of a complex free-energy landscape, characterized by an exponentially large number of metastable minima, is pointed out by the cavity method, at the level of 1-step replica symmetry breaking.

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