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arxiv: 1009.4331 · v1 · pith:6SOUJRCMnew · submitted 2010-09-22 · ❄️ cond-mat.soft · cond-mat.mtrl-sci

Anomalous phase behavior in a model fluid with only one type of local structure

classification ❄️ cond-mat.soft cond-mat.mtrl-sci
keywords anomalousphasebehaviorparticlessystemsableanomaliesassumed
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We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through spherically-symmetric unbounded potentials. Our results show that an extremely weak softening of the interparticle repulsion, yielding a single nearest-neighbor separation, is able to originate a wide spectrum of unconventional features including reentrant melting, solid polymorphism, as well as thermodynamic, dynamic, and structural anomalies. These findings extend the possibility of anomalous phase behavior to a class of systems much broader than currently assumed.

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