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Electrochemical Grafting of Naphthylmethyl Radicals to Epitaxial Graphene: A Versatile Platform to Reversibly Engineer the Band Structure and Transport Properties of Graphene
classification
⚛️ physics.chem-ph
cond-mat.mtrl-sci
keywords
grapheneelectrochemicalgraftingachievealpha-naphthylmethylbandbandgapbeen
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The Kolbe electrochemical oxidation strategy has been utilized to achieve an efficient quasireversible electrochemical grafting of the alpha-naphthylmethyl functional group to graphene. The method facilitates reversible bandgap engineering in graphene and preparation of electrochemically erasable organic dielectric films. The picture shows Raman D-band maps of both systems.
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