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arxiv: 1311.1256 · v2 · pith:C3GHNRRKnew · submitted 2013-11-06 · ❄️ cond-mat.soft · physics.bio-ph· physics.flu-dyn

Scalar φ⁴ field theory for active-particle phase separation

classification ❄️ cond-mat.soft physics.bio-phphysics.flu-dyn
keywords phaseactivebalancecoarseningdetaileddetailed-balancedynamicsfield
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Recent theories predict phase separation among orientationally disordered active particles whose propulsion speed decreases rapidly enough with density. Coarse-grained models of this process show time-reversal symmetry (detailed balance) to be restored for uniform states, but broken by gradient terms; hence detailed-balance violation is strongly coupled to interfacial phenomena. To explore the subtle generic physics resulting from such coupling we here introduce `Active Model B'. This is a scalar $\phi^4$ field theory (or phase-field model) that minimally violates detailed balance via a leading-order square-gradient term. We find that this additional term has modest effects on coarsening dynamics, but alters the static phase diagram by creating a jump in (thermodynamic) pressure across flat interfaces. Both results are surprising, since interfacial phenomena are always strongly implicated in coarsening dynamics but are, in detailed-balance systems, irrelevant for phase equilibria.

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