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arxiv: 1401.6233 · v1 · pith:IT35LQFRnew · submitted 2014-01-24 · ⚛️ physics.atom-ph · physics.atm-clus· physics.chem-ph

Attosecond streaking of Cohen-Fano interferences in the photoionization of H₂^+

classification ⚛️ physics.atom-ph physics.atm-clusphysics.chem-ph
keywords streakingtimeinterferencesattosecondcohen-fanodelayenhancedphotoionization
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We present the first numerical simulation of the time delay in the photoionization of the simplest diatomic molecule H$_2^+$ as observed by attosecond streaking. We show that the strong variation of the Eisenbud-Wigner-Smith time delay as a function of energy and emission angle becomes observable in the streaking time shift provided laser field-induced components are accounted for. The strongly enhanced photoemission time shifts are traced to destructive Cohen-Fano (or two-center) interferences. Signatures of these interferences in the streaking trace are shown to be enhanced when the ionic fragments are detected in coincidence.

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