Attosecond streaking of Cohen-Fano interferences in the photoionization of H₂^+
classification
⚛️ physics.atom-ph
physics.atm-clusphysics.chem-ph
keywords
streakingtimeinterferencesattosecondcohen-fanodelayenhancedphotoionization
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We present the first numerical simulation of the time delay in the photoionization of the simplest diatomic molecule H$_2^+$ as observed by attosecond streaking. We show that the strong variation of the Eisenbud-Wigner-Smith time delay as a function of energy and emission angle becomes observable in the streaking time shift provided laser field-induced components are accounted for. The strongly enhanced photoemission time shifts are traced to destructive Cohen-Fano (or two-center) interferences. Signatures of these interferences in the streaking trace are shown to be enhanced when the ionic fragments are detected in coincidence.
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