Quantum size effect on the paramagnetic critical field in Pb nanofilms

The quantum size effect on the in-plane paramagnetic critical field in Pb nanofilms is investigated with the use of the spin-generalized Bogolubov-de Gennes equations. It is shown that the critical field oscillates as a function of the nanofilm thickness with the period of $\sim2$ ML (even-odd oscillations) modulated by the beating effect. This phenomena is studied in terms of the quantization of the electron energy spectra caused by the confinement of the electron motion in the direction perpendicular to the sample. The calculated values of critical fields for different nanofilm thicknesses are analyzed in the context of Clogston-Chandrasekhar limit. The influence of the thermal effect on the magnetic field induced superconductor to normal metal transition is also discussed. Furthermore, the thickness-dependence of the electron-phonon coupling and its influence on the value of the critical magnetic field are studied.