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arxiv: 1407.5787 · v1 · pith:BI2N67Q7new · submitted 2014-07-22 · ❄️ cond-mat.soft · cond-mat.stat-mech

Strong geometric frustration in model glassformers

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords dynamicstrongfrustrationgeometricglassformersmodelparticularstructural
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We consider three popular model glassformers, the Kob-Andersen and Wahnstr\"om binary Lennard-Jones models and weakly polydisperse hard spheres. Although these systems exhibit a range of fragilities, all feature a rather similar behaviour in their local structure approaching dynamic arrest. In particular we use the dynamic topological cluster classification to extract a locally favoured structure which is particular to each system. These structures form percolating networks, however in all cases there is a strong decoupling between structural and dynamic lengthscales. We suggest that the lack of growth of the structural lengthscale may be related to strong geometric frustration.

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