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arxiv: 1407.7434 · v1 · pith:XQHRPW7Onew · submitted 2014-07-28 · ❄️ cond-mat.stat-mech · math-ph· math.MP

Heat processes in non-equilibrium stochastic systems

classification ❄️ cond-mat.stat-mech math-phmath.MP
keywords non-equilibriumheatmethodsprocessesslowstochasticsystemsthermodynamic
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This thesis is devoted to the theoretical study of slow thermodynamic processes in non-equilibrium stochastic systems. Its main result is a physically and mathematically consistent construction of relevant thermodynamic quantities in the quasistatic limit for a large class of non-equilibrium models. As an application of general methods a natural non-equilibrium generalization of heat capacity is introduced and its properties are analyzed in detail, including an anomalous far-from-equilibrium behavior. The developed methods are further applied to the related problem of time-scale separation where they enable to describe the effective dynamics of both slow and fast degrees of freedom in a more precise way.

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