Predicting Unconventional High Temperature Superconductors in Trigonal Bipyramidal Coordinations

Cuprates and iron-based superconductors are two classes of unconventional high Tc superconductors based on 3d transition elements. Recently, two principles, correspondence principle and magnetic selective pairing rule, have been emerged to unify their high Tc superconducting mechanisms. These principles strongly regulate electronic structures that can host high Tc superconductivity. Guided by these principles, here we propose high Tc superconducting candidates that are formed by cation-anion trigonal bipyramidal complexes with a d^7 filling configuration on the cation ions. Their superconducting states are expected to be dominated by the d+id pairing symmetry.