Why the aspect ratio? Shape equivalence for the extinction spectra of gold nanoparticles
classification
❄️ cond-mat.mtrl-sci
cond-mat.soft
keywords
aspectequivalenceextinctiongoldnanoparticlesratioshapesspectra
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We compare the light extinction spectra of elongated gold nanoparticles with different shapes (cylinder, spherocylinder and ellipsoid) and sizes of 10 to 100~nm. We argue that the equivalence of the various moments of mass distribution is the natural comparison criterion -rather than the length-to-diameter (aspect) ratio generally used in the literature- and that it leads to better spectral correspondence between the various shapes.
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