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arxiv: 1801.03418 · v1 · pith:JBTPLC5Vnew · submitted 2018-01-05 · ❄️ cond-mat.soft · cond-mat.stat-mech

Like-charge attraction in a one-dimensional setting: the importance of being odd

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords like-chargeattractionchargedcounterionslevelmacromoleculesnumberphysics
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From cement cohesion to DNA condensation, a proper statistical physics treatment of systems with long range forces is important for a number of applications in physics, chemistry, and biology. We compute here the effective force between fixed charged macromolecules, screened by oppositely charged mobile ions (counterions). We treat the problem in a one dimensional configuration, that allows for interesting discussion and derivation of exact results, remaining at a level of mathematical difficulty compatible with an undergraduate course. Emphasis is put on the counter-intuitive but fundamental phenomenon of like-charge attraction, that our treatment brings for the first time to the level of undergraduate teaching. The parity of the number of counterions is shown to play a prominent role, which sheds light on the binding mechanism at work when like-charge macromolecules do attract.

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