Noncovalent Functionalization of Black Phosphorus

Gonzalo Abell\'an , Vicent Lloret , Udo Mundloch , Mario Marcia , Christian Neiss , Andreas G\"orling , Maria Varela , Frank Hauke

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Andreas Hirsch

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classification ⚛️ physics.chem-ph cond-mat.mtrl-sci

keywords blackfunctionalizationleadsnon-covalentphosphorusconsiderabledegradationdiimide

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The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other hand, the non-covalent interaction of BP with perylene diimide is mainly due to van-der-Waals interactions but also leads to a considerable stabilization of the BP flakes against oxygen degradation.

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Noncovalent Functionalization of Black Phosphorus

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