Alignment of the CS₂ Dimer Embedded in Helium Droplets Induced by a Circularly Polarized Laser Pulse

Dimers of carbon disulfide (CS$_2$) molecules embedded in helium nanodroplets are aligned using a moderately intense, 160ps, non-resonant, circularly polarized laser pulse. It is shown that the intermolecular carbon-carbon (C-C) axis aligns along the axis perpendicular to the polarization plane of the alignment laser pulse. The degree of alignment, quantified by $\langle \cos^2(\theta_\text{2D}) \rangle$, is determined from the emission directions of recoiling CS$_2$$^+$ fragment ions, created when an intense 40fs probe laser pulse doubly ionizes the dimers. Here, $\theta_\text{2D}$ is the projection of the angle between the C-C axis on the 2D ion detector and the normal to the polarization plane. $\langle \cos^2(\theta_\text{2D}) \rangle$ is measured as a function of the alignment laser intensity and the results agree well with $\langle \cos^2(\theta_\text{2D}) \rangle$ calculated for gas-phase CS$_2$ dimers with a rotational temperature of 0.4K.