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Uniaxial negative thermal expansion in an orthorhombic superconductor CoZr3

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arxiv 2211.13947 v1 pith:FP57W2LO submitted 2022-11-25 cond-mat.mtrl-sci cond-mat.str-elcond-mat.supr-con

classification cond-mat.mtrl-scicond-mat.str-elcond-mat.supr-con
keywords cozr3expansiontemperaturethermalnegativeobservedorthorhombicsuperconductor
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We investigated the temperature evolution of crystal structure of orthorhombic CoZr3, which is a superconductor with a transition temperature of 4.3 K, by synchrotron and laboratory (CuK{\alpha}) X-ray diffraction. Uniaxial negative thermal expansion along the c-axis, which is similar to that observed in tetragonal CoZr2, has been observed at a wide temperature range of T = 90-800 K in CoZr3, while a-and b-axis exhibit positive thermal expansion.

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