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arxiv: cond-mat/0103036 · v1 · submitted 2001-03-01 · ❄️ cond-mat.stat-mech · cond-mat.soft

Criticality in confined ionic fluids

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords confineddensityepsilonionsnegativephasepositivetheory
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A theory of a confined two dimensional electrolyte is presented. The positive and negative ions, interacting by a $1/r$ potential, are constrained to move on an interface separating two solvents with dielectric constants $\epsilon_1$ and $\epsilon_2$. It is shown that the Debye-H\"uckel type of theory predicts that the this 2d Coulomb fluid should undergo a phase separation into a coexisting liquid (high density) and gas (low density) phases. We argue, however, that the formation of polymer-like chains of alternating positive and negative ions can prevent this phase transition from taking place.

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