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arxiv: cond-mat/0201130 · v1 · submitted 2002-01-09 · ❄️ cond-mat.stat-mech · cond-mat.soft

Dynamic Properties of Stretched Water

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords constantdiffusiondynamicspressureswaterchargecomplementarydecreased
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We investigate the dynamics of the extended simple point charge (SPC/E) model of water in the supercooled region. The dynamics at negative pressures show a minimum in the diffusion constant $D$ when the density is decreased at constant temperature, complementary to the known maximum of $D$ at higher pressures. A similar trend in the rotational diffusion is also observed.

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