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arxiv: cond-mat/0309190 · v1 · submitted 2003-09-08 · ❄️ cond-mat.stat-mech · cond-mat.soft

Homogeneous Nucleation in Inhomogeneous Media II: Nucleation in a Shear Flow

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords flownucleationclustershearcoefficientcondensationcrystallizationderive
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We investigate the influence of a shear flow on the process of nucleation. Mesoscopic nonequilibrium thermodynamics is used to derive the Fokker-Planck equation governing the evolution of the cluster size distribution in a metastable phase subjected to a stationary flow. The presence of the flow manifests itself in the expression for the effective diffusion coefficient of a cluster and introduces modifications in the nucleation rate. The implications of these results in condensation and polymer crystallization are discussed.

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