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arxiv: cond-mat/0310678 · v1 · submitted 2003-10-29 · ❄️ cond-mat.soft · cond-mat.stat-mech

Chiral molecule adsorption on helical polymers

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords adsorptionaminehelicitychiralinductionmodelmoleculespolymer
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We present a lattice model for helicity induction on an optically inactive polymer due to the adsorption of exogenous chiral amine molecules. The system is mapped onto a one-dimensional Ising model characterized by an on-site polymer helicity variable and an amine occupancy one. The equilibrium properties are analyzed at the limit of strong coupling between helicity induction and amine adsorption and that of non-interacting adsorbant molecules. We discuss our results in view of recent experimental results.

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