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arxiv: cond-mat/0311286 · v1 · submitted 2003-11-12 · ❄️ cond-mat.stat-mech · cond-mat.soft

Anomalous dynamics of confined water at low hydration

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords moleculestimewateranomalousbehaviourconfineddynamicshydration
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The mobility of water molecules confined in a silica pore is studied by computer simulation in the low hydration regime, where most of the molecules reside close to the hydrophilic substrate. A layer analysis of the single particle dynamics of these molecules shows an anomalous diffusion with a sublinear behaviour at long time. This behaviour is strictly connected to the long time decay of the residence time distribution analogously to water at contact with proteins.

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