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arxiv: cond-mat/0312194 · v2 · submitted 2003-12-08 · ❄️ cond-mat.soft · cond-mat.stat-mech

Effective interactions between star polymers

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords potentialarmseffectiveequalfindnumberpolymerssoft
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We study numerically the effective pair potential between star polymers with equal arm lengths and equal number $f$ of arms. The simulations were done for the soft core Domb-Joyce model on the simple cubic lattice, to minimize corrections to scaling and to allow for an unlimited number of arms. For the sampling, we used the pruned-enriched Rosenbluth method (PERM). We find that the potential is much less soft than claimed in previous papers, in particular for $f\gg 1$. While we verify the logarithmic divergence of $V(r)$, with $r$ being the distance between the two cores, predicted by Witten and Pincus, we find for $f>20$ that the Mayer function is hardly distinguishable from that for a Gaussian potential.

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