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arxiv: cond-mat/0501432 · v1 · submitted 2005-01-18 · ❄️ cond-mat.stat-mech · cond-mat.soft

Depletion interactions of non-spherical colloidal particles in polymer solutions

classification ❄️ cond-mat.stat-mech cond-mat.soft
keywords particlesanisotropiccolloidaldepletioninteractionpolymerpolymerscalculate
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We consider anisotropic colloidal particles immersed in a solution of long, flexible, and nonadsorbing polymers. For the dumbbell shapes of recently synthesized particles consisting of two intersecting spheres and for lens-shaped particles with spherical surfaces we calculate the isotropic and anisotropic interaction parameters that determine the immersion free energy and the orientation-dependent depletion interaction between particles that are induced by the polymers. Exact results are obtained for random-walk like (ideal) polymer chains.

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