On the superconducting state of the organic conductor (TMTSF)₂ClO₄

$(TMTSF)_2ClO_4$ is a quasi-one dimensional organic conductor and superconductor with $T_c=1.4$K, and one of at least two Bechgaard salts observed to have upper critical fields far exceeding the paramagnetic limit. Nevertheless, the $^{77}$Se NMR Knight shift at low fields reveals a decrease in spin susceptibility $\chi_s$ consistent with singlet spin pairing. The field dependence of the spin-lattice relaxation rate at 100mK exhibits a sharp crossover (or phase transition) at a field $H_s\sim15$kOe, to a regime where $\chi_s$ is close to the normal state value, even though \hc2 $\gg H_s$.