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arxiv: cond-mat/9712117 · v1 · submitted 1997-12-11 · ❄️ cond-mat.soft · cond-mat.mtrl-sci

A variational approach to necklaces formation in polyelectrolytes

classification ❄️ cond-mat.soft cond-mat.mtrl-sci
keywords approachchainstructurevariationalcollapsesconditionsformationglobules
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By means of a variational approach we study the conditions under which a polyelectrolyte in a bad solvent will undergo a transition from a rod-like structure to a ``necklace'' structure in which the chain collapses into a series of globules joined by stretched chain segments.

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