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arxiv: cond-mat/9812249 · v3 · submitted 1998-12-15 · ❄️ cond-mat · chao-dyn· nlin.CD· physics.chem-ph

Statistics of photodissociation spectra: nonuniversal properties

classification ❄️ cond-mat chao-dynnlin.CDphysics.chem-ph
keywords correlationfunctionnonuniversalphotodissociationresonancestwo-pointabovebehavior
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We consider the two-point correlation function of the photodissociation cross section in molecules where the fragmentation process is indirect, passing through resonances above the dissociation threshold. In the limit of overlapping resonances, a formula is derived, relating this correlation function to the behavior of the corresponding classical system. It is shown that nonuniversal features of the two-point correlation function may have significant experimental manifestations.

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