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arxiv: cond-mat/9910329 · v3 · submitted 1999-10-21 · ❄️ cond-mat · physics.chem-ph

A superfluid hydrodynamic model for the enhanced moments of inertia of molecules in liquid 4He

classification ❄️ cond-mat physics.chem-ph
keywords deltaliquidmodelmoleculesdensityhydrodynamicinertiamolecule
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We present a superfluid hydrodynamic model for the increase in moment of inertia, $\Delta I$, of molecules rotating in liquid $^4$He. The static inhomogeneous He density around each molecule (calculated using the Orsay-Paris liquid $^4$He density functional) is assumed to adiabatically follow the rotation of the molecule. We find that the $\Delta I$ values created by the viscousless and irrotational flow are in good agreement with the observed increases for several molecules [ OCS, (HCN)$_2$, HCCCN, and HCCCH$_3$ ]. For HCN and HCCH, our model substantially overestimates $\Delta I$. This is likely to result from a (partial) breakdown of the adiabatic following approximation.

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