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arxiv: cond-mat/9912239 · v1 · submitted 1999-12-14 · ❄️ cond-mat.mtrl-sci · cond-mat.soft

Surface defreezing of glasses

classification ❄️ cond-mat.mtrl-sci cond-mat.soft
keywords surfacebulkglassdefreezingflowinterfacetransitionacross
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A glass surface may still flow below the bulk glass transition temperature, where the underlying bulk is frozen. Assuming the existence at T=T* of a bulk thermodynamical glass transition, we show that the glass-vapor interface is generally wetted by a liquid layer of thickness ~ -ln(T*-T) when T--> T*. Contrary to standard surface melting of crystals however, the integrated value of the diffusivity across the interface remains finite for T-->T*. Difference in shape induced by bulk and by surface flow is discussed as a possible means of experimental detection of surface defreezing.

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