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arxiv: physics/0103036 · v2 · submitted 2001-03-13 · ⚛️ physics.atom-ph · physics.atm-clus· physics.chem-ph

Convergent variational calculation of positronium-hydrogen-atom scattering lengths

classification ⚛️ physics.atom-ph physics.atm-clusphysics.chem-ph
keywords convergentscatteringatomlengthsvariationalachievingappropriateatomic
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We present a convergent variational basis-set calculational scheme for elastic scattering of positronium atom by hydrogen atom in S wave. Highly correlated trial functions with appropriate symmetry are needed for achieving convergence. We report convergent results for scattering lengths in atomic units for both singlet ($=3.49\pm 0.20$) and triplet ($=2.46\pm 0.10$) states.

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