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arxiv: physics/0109017 · v1 · submitted 2001-09-06 · ⚛️ physics.chem-ph · physics.comp-ph

Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential

classification ⚛️ physics.chem-ph physics.comp-ph
keywords calculationscalculationeffectsfactorsfranck-condonmorsenon-condonpotential
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The calculation of Franck-Condon factors between different one-dimensional Morse potential eigenstates using a formula derived from the Wigner function is discussed. Our numerical calculations using a very simple program written in Mathematica is compared with other calculations. We show that our results have a similar accuracy as the calculations performed with more sophisticated methods. We discuss the extension of our method to include non-Condon effects in the calculation.

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