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arxiv: physics/0306058 · v1 · submitted 2003-06-06 · ⚛️ physics.atm-clus · nucl-th

Variational RPA for the Mie resonance in jellium

classification ⚛️ physics.atm-clus nucl-th
keywords shiftspill-outcorrectionenergysimplevariationaladditionalanalytic
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The surface plasmon in simple metal clusters is red-shifted from the Mie frequency, the energy shift being significantly larger than the usual spill-out correction. Here we develop a variational approach to the RPA collective excitations. Using a simple trial form, we obtain analytic expressions for the energy shift beyond the spill-out contribution. We find that the additional red shift is proportional to the spill-out correction and can have the same order of magnitude.

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