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Photoionization of atoms stuffed inside a two-shell fullerene
Atomic and Molecular Clusters · Submitted 12 Apr 2009
abstract compiled · 2026-09-23 · no language-model review
The authors' main claim A whole variety of new peculiarities are found that deserve experimental verification.
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The paper's own sentences, arranged. Each label is drawn from a closed vocabulary; the number beside it is the probability the classifier gave that label. Numbers in the tables are the authors', checked by code. No sentence in this record was written by a model.
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The abstract, sentence by sentence
The photoionization of a two-shell endohedral A@CN1@CN2 is considered. Formulas are presented for cross-sections and angular anisotropy parameters, both dipole and non-dipole. The effect of the fullerenes shell upon photoelectron from atom A is taken into account substituting the action of the fullerene by two zero-thickness "bubble potential". The fullerenes shells polarization is included assuming that the radius of the outer shell R2 is much bigger than the inner R1 and both much exceeds the atomic radius r. This permits to express the effect via CN1,N2 polarizabilities, which are connected to their photoionization cross-sections. The interaction between shells CN1 and CN2 is taken into account in the Random Phase Approximation (RPA). The effect of photoelectron scattering by both "bubble potentials" is included in the lowest order and in the RPA frame. As concrete examples, two endohedrals Ar@C60@C240 and Xe@C60@C240 are considered. In the first case we consider 3p and 3s, while in the second 5p, 5s and 4d subshells. A whole variety of new peculiarities are found that deserve experimental verification.
background contribution method result interpretation main claim
| # | sentence | role | the authors' own work | states the main conclusion | strength |
|---|---|---|---|---|---|
| s0 | The photoionization of a two-shell endohedral A@CN1@CN2 is considered. | contribution 0.76 | 0.49 | 0.04 | asserted 0.80 |
| s1 | Formulas are presented for cross-sections and angular anisotropy parameters, both dipole and non-dipole. | contribution 0.88 | 0.88 | 0.06 | asserted 0.99 |
| s2 | The effect of the fullerenes shell upon photoelectron from atom A is taken into account substituting the action of the fullerene by two zero-thickness "bubble potential". | method 0.99 | 0.78 | 0.05 | asserted 0.99 |
| s3 | The fullerenes shells polarization is included assuming that the radius of the outer shell R2 is much bigger than the inner R1 and both much exceeds the atomic radius r. | method 0.98 | 0.63 | 0.03 | asserted 0.98 |
| s4 | This permits to express the effect via CN1,N2 polarizabilities, which are connected to their photoionization cross-sections. | method 0.94 | 0.79 | 0.08 | asserted 0.90 |
| s5 | The interaction between shells CN1 and CN2 is taken into account in the Random Phase Approximation (RPA). | method 0.99 | 0.80 | 0.04 | asserted 1.00 |
| s6 | The effect of photoelectron scattering by both "bubble potentials" is included in the lowest order and in the RPA frame. | method 0.98 | 0.87 | 0.05 | asserted 1.00 |
| s7 | As concrete examples, two endohedrals Ar@C60@C240 and Xe@C60@C240 are considered. | contribution 0.60 | 0.77 | 0.04 | asserted 0.96 |
| s8 | In the first case we consider 3p and 3s, while in the second 5p, 5s and 4d subshells. | contribution 0.66 | 0.72 | 0.04 | asserted 0.97 |
| s9 | A whole variety of new peculiarities are found that deserve experimental verification. | result 0.39 | 0.91 | 0.46 | asserted 0.97 |
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Original abstract
The photoionization of a two-shell endohedral A@CN1@CN2 is considered. Formulas are presented for cross-sections and angular anisotropy parameters, both dipole and non-dipole. The effect of the fullerenes shell upon photoelectron from atom A is taken into account substituting the action of the fullerene by two zero-thickness "bubble potential". The fullerenes shells polarization is included assuming that the radius of the outer shell R2 is much bigger than the inner R1 and both much exceeds the atomic radius r. This permits to express the effect via CN1,N2 polarizabilities, which are connected to their photoionization cross-sections. The interaction between shells CN1 and CN2 is taken into account in the Random Phase Approximation (RPA). The effect of photoelectron scattering by both "bubble potentials" is included in the lowest order and in the RPA frame. As concrete examples, two endohedrals Ar@C60@C240 and Xe@C60@C240 are considered. In the first case we consider 3p and 3s, while in the second 5p, 5s and 4d subshells. A whole variety of new peculiarities are found that deserve experimental verification.
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