Fluctuation-theory constraint for extensive entropy in Monte-Carlo simulations
classification
❄️ cond-mat.stat-mech
cond-mat.mes-hall
keywords
energyentropyconstraintdependentextensivefluctuationsmonte-carlosimulations
read the original abstract
The entropy per particle in most Monte-Carlo simulations is size dependent due to correlated energy fluctuations. Guided by nanothermodynamics, we find a constraint for the Ising model that enhances the fluctuations and lowers the free energy, while making the entropy homogeneous, additive, and extensive. Although the average interaction energy becomes size dependent, the resulting distribution of energies provides a mechanism for the heterogeneity found in the dynamics of many materials.
This paper has not been read by Pith yet.
discussion (0)
Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.