pith. sign in

arxiv: 0905.3855 · v1 · submitted 2009-05-23 · ❄️ cond-mat.soft · cond-mat.stat-mech

Strong Coupling Electrostatics in the Presence of Dielectric Inhomogeneities

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords dielectriccentralcounterioneffectsmembranemismatchstrongtheory
0
0 comments X
read the original abstract

We study the strong-coupling (SC) interaction between two like-charged membranes of finite thickness embedded in a medium of higher dielectric constant. A generalized SC theory is applied along with extensive Monte-Carlo simulations to study the image charge effects induced by multiple dielectric discontinuities in this system. These effects lead to strong counterion crowding in the central region of the inter-surface space upon increasing the solvent/membrane dielectric mismatch and change the membrane interactions from attractive to repulsive at small separations. These features agree quantitatively with the SC theory at elevated couplings or dielectric mismatch where the correlation hole around counterions is larger than the thickness of the central counterion layer.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.