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Molecular Structure and Electrophysical Properties of Pentacene Thioderivatives

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Paper breakdownThe authors' claims, conditions and measurements, as JSON Signed receiptProof this review has not been altered
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M. P. Gorishnyi

Soft Condensed Matter · Submitted 9 Apr 2014

abstract compiled · 2026-09-23 · no language-model review

The authors' main claim The analysis of the photocurrent and capacitor photovoltage (CPV) spectra in the range of the first electron transitions in PTPn has shown that the photoconductivity is of the hole type and is caused by the dissociation of excitons at the electron capture centers.

how it is stated · asserted 1.00 read the record →

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arXiv ID1404.2489 (version 2)
Pith IDME4UEAY5, Pith's permanent record of this paper and its review
CitationM. P. Gorishnyi. "Molecular Structure and Electrophysical Properties of Pentacene Thioderivatives." arXiv:1404.2489 (2014). https://pith.science/paper/ME4UEAY5
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The compiled record

The paper's own sentences, arranged. Each label is drawn from a closed vocabulary; the number beside it is the probability the classifier gave that label. Numbers in the tables are the authors', checked by code. No sentence in this record was written by a model.

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Compiled by classifier-1.13-20260917 via OpenRouter, question bank abstract-p1-20260923, 2026-09-23: 1 request, 5,767 input tokens, $0.0002 reported.

What the abstract itself states, as probabilities: claims first 0.03 · states limitation 0.08 · human participants 0.02 · controlled comparison 0.03 · randomized assignment 0.01 · states quantitative result 0.18 · compares with prior results 0.05 · mentions code or data availability 0.02.

The abstract, sentence by sentence

arXiv listing abstract v2. Results and the main claim are underlined; .

Possible conformations of the thioderivatives of pentacene (Pn) have been considered. The absorption spectra of polythiopentacene (PTPn) solutions and films have been studied. PTPn is revealed to be a mixture of Pn thioderivatives with different numbers of S atoms. After this mixture having been condensed in vacuum onto quartz substrates, its main components are tetrathiopentacene (TTPn) and hexathiopentacene (HTPn). The position of the maximum in the long-wave absorption bands of Pn thioderivatives is a linear function of the number of valence electrons in S atoms, which take part in the conjugation with the {\pi}-system of the pentacene frame of PTPn molecules. The analysis of the photocurrent and capacitor photovoltage (CPV) spectra in the range of the first electron transitions in PTPn has shown that the photoconductivity is of the hole type and is caused by the dissociation of excitons at the electron capture centers. The frontal CPV is caused by the Dember photovoltage ({\phi}D), and the back one by the surface-barrier photovoltage ({\phi}b).

background contribution method result interpretation main claim

What the classifier reports for each sentence. The number is the probability it gave the label.
#sentencerolethe authors' own workstates the main conclusionstrength
s0 Possible conformations of the thioderivatives of pentacene (Pn) have been considered. contribution 0.67 0.73 0.03 hedged possibility 0.44
s1 The absorption spectra of polythiopentacene (PTPn) solutions and films have been studied. contribution 0.61 0.89 0.04 asserted 0.99
s2 PTPn is revealed to be a mixture of Pn thioderivatives with different numbers of S atoms. result 0.98 0.84 0.16 asserted 1.00
s3 After this mixture having been condensed in vacuum onto quartz substrates, its main components are tetrathiopentacene (TTPn) and hexathiopentacene (HTPn). result 0.80 0.86 0.10 asserted 1.00
s4 The position of the maximum in the long-wave absorption bands of Pn thioderivatives is a linear function of the number of valence electrons in S atoms, which take part in the conjugation with the {\pi}-system of the pentacene frame of PTPn molecules. result 0.96 0.81 0.30 asserted 1.00
s5 The analysis of the photocurrent and capacitor photovoltage (CPV) spectra in the range of the first electron transitions in PTPn has shown that the photoconductivity is of the hole type and is caused by the dissociation of excitons at the electron capture centers. result 0.76 0.93 0.29 asserted 1.00
s6 The frontal CPV is caused by the Dember photovoltage ({\phi}D), and the back one by the surface-barrier photovoltage ({\phi}b). result 0.52 0.80 0.07 asserted 1.00

What kind of paper the classifier reports this is: empirical study 1.00 · evidence from observation or experiment 1.00.

What was examined, and what was not

sources read
  • arXiv listing abstract v2
not examined
  • full text
  • figures and tables
  • references and citing sentences
  • relations to other papers
levels run
  • P abstract
not run
  • S sections
  • T body sentences
  • C citations
  • R cross-paper relations

Every quoted sentence on this record is the authors'. Every label is from Pith's closed vocabulary, with the probability shown beside it. Every number in the measurements table is the authors', checked by code. Record as JSON

The paper
Original abstract

Possible conformations of the thioderivatives of pentacene (Pn) have been considered. The absorption spectra of polythiopentacene (PTPn) solutions and films have been studied. PTPn is revealed to be a mixture of Pn thioderivatives with different numbers of S atoms. After this mixture having been condensed in vacuum onto quartz substrates, its main components are tetrathiopentacene (TTPn) and hexathiopentacene (HTPn). The position of the maximum in the long-wave absorption bands of Pn thioderivatives is a linear function of the number of valence electrons in S atoms, which take part in the conjugation with the {\pi}-system of the pentacene frame of PTPn molecules. The analysis of the photocurrent and capacitor photovoltage (CPV) spectra in the range of the first electron transitions in PTPn has shown that the photoconductivity is of the hole type and is caused by the dissociation of excitons at the electron capture centers. The frontal CPV is caused by the Dember photovoltage ({\phi}D), and the back one by the surface-barrier photovoltage ({\phi}b).

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