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Dynamic Theory of Polydomain Liquid-Crystal Elastomers
Soft Condensed Matter · Submitted 26 Feb 2015
abstract compiled · 2026-09-23 · no language-model review
The authors' main claim As an alternative explanation, we develop a theory for the dynamics of the isotropic-nematic transition in liquid-crystal elastomers, and show that the dynamics can induce a polydomain structure with a characteristic length scale, through a mechanism analogous to the Cahn-Hilliard equation for phase separation.
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The abstract, sentence by sentence
When liquid-crystal elastomers are prepared without any alignment, disordered polydomain structures emerge as the materials are cooled into the nematic phase. These polydomain structures have been attributed to quenched disorder in the cross-linked polymer network. As an alternative explanation, we develop a theory for the dynamics of the isotropic-nematic transition in liquid-crystal elastomers, and show that the dynamics can induce a polydomain structure with a characteristic length scale, through a mechanism analogous to the Cahn-Hilliard equation for phase separation.
background contribution method result interpretation main claim
| # | sentence | role | the authors' own work | states the main conclusion | strength |
|---|---|---|---|---|---|
| s0 | When liquid-crystal elastomers are prepared without any alignment, disordered polydomain structures emerge as the materials are cooled into the nematic phase. | background 0.99 | 0.25 | 0.03 | asserted 1.00 |
| s1 | These polydomain structures have been attributed to quenched disorder in the cross-linked polymer network. | background 0.99 | 0.06 | 0.03 | asserted 0.92 |
| s2 | As an alternative explanation, we develop a theory for the dynamics of the isotropic-nematic transition in liquid-crystal elastomers, and show that the dynamics can induce a polydomain structure with a characteristic length scale, through a mechanism analogous to the Cahn-Hilliard equation for phase separation. | contribution 0.99 | 0.95 | 0.83 | asserted 1.00 |
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The paper
Original abstract
When liquid-crystal elastomers are prepared without any alignment, disordered polydomain structures emerge as the materials are cooled into the nematic phase. These polydomain structures have been attributed to quenched disorder in the cross-linked polymer network. As an alternative explanation, we develop a theory for the dynamics of the isotropic-nematic transition in liquid-crystal elastomers, and show that the dynamics can induce a polydomain structure with a characteristic length scale, through a mechanism analogous to the Cahn-Hilliard equation for phase separation.
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