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Non-Perturbative Theory of Dispersion Interactions

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arxiv 1502.07850 v1 pith:635VCDRZ submitted 2015-02-27 quant-ph physics.chem-ph

classification quant-phphysics.chem-ph
keywords theorydispersionforcenon-perturbativeperturbativeaccountadditionapproximations
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Some open questions exist with fluctuation-induced forces between extended dipoles. Conventional intuition derives from large-separation perturbative approximations to dispersion force theory. Here we present a full non-perturbative theory. In addition we discuss how one can take into account finite dipole size corrections. It is of fundamental value to investigate the limits of validity of the perturbative dispersion force theory.

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