High-bit-rate quantum key distribution with entangled internal degrees of freedom of photons

Quantum communication over long distances is integral to information security and has been demonstrated in free space and fibre with two-dimensional polarisation states of light. Although increased bit rates can be achieved using high-dimensional encoding with spatial modes of light, the efficient detection of high-dimensional states remains a challenge to realise the full benefit of the increased state space. Here we exploit the entanglement between spatial modes and polarization to realise a four-dimensional quantum key distribution (QKD) protocol. We introduce a detection scheme which employs only static elements, allowing for the detection of all basis modes in a high-dimensional space deterministically. As a result we are able to realise the full potential of our high-dimensional state space, demonstrating efficient QKD at high secure key and sift rates, with the highest capacity-to-dimension reported to date. This work opens the possibility to increase the dimensionality of the state-space indefinitely while still maintaining deterministic detection and will be invaluable for long distance 'secure and fas' data transfer.