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Kitaev Materials
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abstract
In transition-metal compounds with partially filled $4d$ and $5d$ shells spin-orbit entanglement, electronic correlations, and crystal-field effects conspire to give rise to a variety of novel forms of topological quantum matter. This includes Kitaev materials -- a family of spin-orbit assisted Mott insulators, in which local, spin-orbit entangled $j=1/2$ moments form that are subject to strong bond-directional interactions. On a conceptual level, Kitaev materials attract much interest for their unconventional forms of magnetism, such as spin liquid physics in two- and three-dimensional lattice geometries or the formation of non-trivial spin textures. Experimentally, a number of Kitaev materials have been synthesized, which includes the honeycomb materials Na$_2$IrO$_3$, $\alpha$-Li$_2$IrO$_3$, and RuCl$_3$, the triangular materials Ba$_3$Ir$_x$Ti$_{3-x}$O$_9$, as well as the three-dimensional hyper-honeycomb and stripy-honeycomb materials $\beta$-Li$_2$IrO$_3$ and $\gamma$-Li$_2$IrO$_3$. These lecture notes provide a short review of the current status of the theoretical and experimental exploration of these Kitaev materials.
Forward citations
Cited by 11 Pith papers
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Non-Abelian chiral spin liquid on a simple non-Archimedean lattice
The Kitaev model on the pentaheptite lattice is exactly solvable and hosts a non-Abelian chiral spin liquid with spontaneous time reversal symmetry breaking.
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Signatures of Non-Abelian Kitaev quantum spin liquids in noise magnetormetry
NV-center T1 noise magnetometry should show a sharp relaxation enhancement when its frequency matches the energy gap between a vacancy-bound Majorana zero mode and a low-energy hybridized Majorana mode in a non-Abelia...
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High-Field Quantum Disordered State in $\alpha$-RuCl3: Spin Flips, Bound States, and a Multi-Particle Continuum
The high-field phase of α-RuCl3 is a partially polarized quantum disordered state with a single spin-flip mode, a two-particle bound state, and a gapped continuum.
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Origin of the insulating state in the Kitaev candidate Cu$_2$IrO$_3$
The insulating state of Cu2IrO3 is proposed to originate from Ir3+/Ir4+ charge ordering that forms two interpenetrated triangular lattices of magnetic Ir4+ and Cu2+ ions.
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Spin-liquid-based topological qubits
A blueprint for two scalable spin-liquid-based topological qubit architectures, complete with protocols for anyon creation, readout, braiding, and gates.
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Two-Magnon Bound States in the Kitaev Model in a $[111]$-Field
In the Kitaev model in a [111] field, the two-magnon bound-state gap lies below the single-magnon gap in the spin liquid and the pair gap controls the transition into the polarized phase.
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Quantum Spin Liquid in a depleted triangular lattice Iridate K$_x$Ir$_y$O$_2$
Measurements on the new layered iridate K0.85Ir0.79O2 show no magnetic order down to 1.8 K and a T-linear heat capacity, consistent with a gapless quantum spin liquid.
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Magnetic field induced quantum phases in a tensor network study of Kitaev magnets
In the K-Γ-Γ' model for α-RuCl3, the chiral Kitaev spin liquid survives only in a small corner, while new nematic paramagnet phases dominate the intermediate magnetic-field regime.
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Resonant inelastic x-ray scattering study of $\alpha$-RuCl$_3$: a progress report
Ru M3-edge RIXS on α-RuCl3 reveals a single unsplit spin-orbit exciton at 231 meV, yielding λ=154±2 meV and an upper bound |Δ|<65 meV on trigonal distortion, consistent with jeff=1/2 physics.
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Fractional excitations in Kitaev quasi-one-dimensional chain
A quasi-1D Kitaev chain from truncated honeycomb shows chiral topological phases with protected edge modes in BDI class and broad continua from fractional excitations in dynamical spin correlations.
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Hunting Majorana Fermions in Kitaev Magnets
A review of theoretical and experimental evidence that Kitaev magnets exhibit thermal fractionalization into Majorana fermions and Z2 fluxes, with the half-quantized thermal Hall effect as the strongest proposed signature.
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