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Zeeman interaction and Jahn-Teller effect in $\Gamma_8$ multiplet
Materials Science · Submitted 30 May 2017
abstract compiled · 2026-09-23 · no language-model review
The authors' main claim We find that in the presence of dynamical Jahn-Teller effect, the Zeeman interaction remains isotropic, whereas the $g$ and $G$ factors can change their signs.
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The abstract, sentence by sentence
We present a thorough analysis of the interplay of magnetic moment and the Jahn-Teller effect in the $\Gamma_8$ cubic multiplet. We find that in the presence of dynamical Jahn-Teller effect, the Zeeman interaction remains isotropic, whereas the $g$ and $G$ factors can change their signs. The static Jahn-Teller distortion also can change the sign of these $g$ factors as well as the nature of the magnetic anisotropy. Combining the theory with state-of-the-art {\it ab initio} calculations, we analyzed the magnetic properties of Np$^{4+}$ and Ir$^{4+}$ impurity ions in cubic environment. The calculated $g$ factors of Np$^{4+}$ impurity agree well with experimental data. The {\it ab initio} calculation predicts strong Jahn-Teller effect in Ir$^{4+}$ ion in cubic environment and the strong vibronic reduction of $g$ and $G$ factors.
background contribution method result interpretation main claim
| # | sentence | role | the authors' own work | states the main conclusion | strength |
|---|---|---|---|---|---|
| s0 | We present a thorough analysis of the interplay of magnetic moment and the Jahn-Teller effect in the $\Gamma_8$ cubic multiplet. | contribution 1.00 | 0.93 | 0.10 | asserted 0.90 |
| s1 | We find that in the presence of dynamical Jahn-Teller effect, the Zeeman interaction remains isotropic, whereas the $g$ and $G$ factors can change their signs. | result 1.00 | 0.95 | 0.51 | asserted 1.00 |
| s2 | The static Jahn-Teller distortion also can change the sign of these $g$ factors as well as the nature of the magnetic anisotropy. | result 1.00 | 0.80 | 0.16 | hedged possibility 0.93 |
| s3 | Combining the theory with state-of-the-art {\it ab initio} calculations, we analyzed the magnetic properties of Np$^{4+}$ and Ir$^{4+}$ impurity ions in cubic environment. | method 0.67 | 0.95 | 0.05 | asserted 0.99 |
| s4 | The calculated $g$ factors of Np$^{4+}$ impurity agree well with experimental data. | result 0.99 | 0.89 | 0.08 | asserted 0.99 |
| s5 | The {\it ab initio} calculation predicts strong Jahn-Teller effect in Ir$^{4+}$ ion in cubic environment and the strong vibronic reduction of $g$ and $G$ factors. | result 1.00 | 0.92 | 0.18 | asserted 0.99 |
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The paper
Original abstract
We present a thorough analysis of the interplay of magnetic moment and the Jahn-Teller effect in the $\Gamma_8$ cubic multiplet. We find that in the presence of dynamical Jahn-Teller effect, the Zeeman interaction remains isotropic, whereas the $g$ and $G$ factors can change their signs. The static Jahn-Teller distortion also can change the sign of these $g$ factors as well as the nature of the magnetic anisotropy. Combining the theory with state-of-the-art {\it ab initio} calculations, we analyzed the magnetic properties of Np$^{4+}$ and Ir$^{4+}$ impurity ions in cubic environment. The calculated $g$ factors of Np$^{4+}$ impurity agree well with experimental data. The {\it ab initio} calculation predicts strong Jahn-Teller effect in Ir$^{4+}$ ion in cubic environment and the strong vibronic reduction of $g$ and $G$ factors.
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