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Capillary interfacial tension in active phase separation

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arxiv 2103.15563 v2 pith:LJXF7BEQ submitted 2021-03-29 cond-mat.soft cond-mat.stat-mech

classification cond-mat.softcond-mat.stat-mech
keywords activecapillaryinterfacialtensionfluctuationsmodelphaserate
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abstract

In passive fluid-fluid phase separation, a single interfacial tension sets both the capillary fluctuations of the interface and the rate of Ostwald ripening. We show that these phenomena are governed by two different tensions in active systems, and compute the capillary tension $\sigma_{cw}$ which sets the relaxation rate of interfacial fluctuations in accordance with capillary wave theory. We discover that strong enough activity can cause negative $\sigma_{cw}$. In this regime, depending on the global composition, the system self-organizes, either into a microphase-separated state in which coalescence is highly inhibited, or into an `active foam' state. Our results are obtained for Active Model B+, a minimal continuum model which, although generic, admits significant analytical progress.

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    In a conserved active emulsion, repulsive chemotaxis causes a stationary or oscillatory interfacial instability; the oscillatory instability creates persistent capillary waves with theoretically predicted and numerica...

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