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Universal excitonic superexchange in spin-orbit-coupled Mott insulators
Strongly Correlated Electrons · Submitted 11 Oct 2021
abstract compiled · 2026-09-23 · no language-model review
The authors' main claim We point out the universal presence of the excitonic superexchange in spin-orbit-coupled Mott insulators.
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We point out the universal presence of the excitonic superexchange in spin-orbit-coupled Mott insulators. It is observed that, the restriction to the lowest spin-orbit-entangled "$J$" states may sometimes be insufficient to characterize the microscopic physics, and the virtual excitonic processes via the upper "$J$" states provide an important correction to the superexchange. We illustrate this excitonic superexchange from a two-dimensional $5d$ iridate Sr$_2$IrO$_4$ and explain its physical consequences such as the orbital-like coupling to the external magnetic flux and the nonlinear magnetic susceptibility. The universal presence of the excitonic superexchange in other spin-orbit-coupled Mott insulators such as $3d$ Co-based Kitaev magnets and even $f$ electron rare-earth magnets is further discussed.
background contribution method result interpretation main claim
| # | sentence | role | the authors' own work | states the main conclusion | strength |
|---|---|---|---|---|---|
| s0 | We point out the universal presence of the excitonic superexchange in spin-orbit-coupled Mott insulators. | contribution 0.70 | 0.81 | 0.90 | asserted 1.00 |
| s1 | It is observed that, the restriction to the lowest spin-orbit-entangled "$J$" states may sometimes be insufficient to characterize the microscopic physics, and the virtual excitonic processes via the upper "$J$" states provide an important correction to the superexchange. | result 0.69 | 0.51 | 0.12 | hedged possibility 0.95 |
| s2 | We illustrate this excitonic superexchange from a two-dimensional $5d$ iridate Sr$_2$IrO$_4$ and explain its physical consequences such as the orbital-like coupling to the external magnetic flux and the nonlinear magnetic susceptibility. | contribution 0.89 | 0.83 | 0.09 | asserted 1.00 |
| s3 | The universal presence of the excitonic superexchange in other spin-orbit-coupled Mott insulators such as $3d$ Co-based Kitaev magnets and even $f$ electron rare-earth magnets is further discussed. | contribution 0.74 | 0.57 | 0.13 | asserted 0.63 |
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Original abstract
We point out the universal presence of the excitonic superexchange in spin-orbit-coupled Mott insulators. It is observed that, the restriction to the lowest spin-orbit-entangled "$J$" states may sometimes be insufficient to characterize the microscopic physics, and the virtual excitonic processes via the upper "$J$" states provide an important correction to the superexchange. We illustrate this excitonic superexchange from a two-dimensional $5d$ iridate Sr$_2$IrO$_4$ and explain its physical consequences such as the orbital-like coupling to the external magnetic flux and the nonlinear magnetic susceptibility. The universal presence of the excitonic superexchange in other spin-orbit-coupled Mott insulators such as $3d$ Co-based Kitaev magnets and even $f$ electron rare-earth magnets is further discussed.
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See details in the Supplementary Material http://stacks.iop.org/0295-5075/139/56001/mmedia Supplementarymaterial.pdf (SM), which includes refs.~ [ref] .
$\texttt{Spglib}$: a software library for crystal symmetry search · Introduction · 0.99
Cites as background 1 paper
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The latter covers the $4d$/$5d$ magnets like Kitaev materials, iridates, osmates [ref] , $4f$ rare-earth magnets [ref] , or even $3d$ Co-based Kitaev magnets and Ni-based diamond antiferromagnets that are of some recent interest [ref] .
Kitaev Materials · Introduction · 0.99
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