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Driving non-trivial quantum phases in conventional semiconductors with intense excitonic fields

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arxiv 2403.08725 v1 pith:RS2XUSN4 submitted 2024-03-13 cond-mat.mtrl-sci cond-mat.mes-hall

classification cond-mat.mtrl-scicond-mat.mes-hall
keywords quantumexcitonicexcitonsfieldsintensephasesphenomenaconventional
verification ladder T0 review T1 audit T2 compute T3 formal
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Inducing novel quantum phases and topologies in materials using intense light fields is a key objective of modern condensed matter physics, but nonetheless faces significant experimental challenges. Alternately, theory predicts that in the dense limit, excitons - collective excitations composed of Coulomb-bound electron-hole pairs - could also drive exotic quantum phenomena. However, the direct observation of these phenomena requires the resolution of electronic structure in momentum space in the presence of excitons, which became possible only recently. Here, using time- and angle-resolved photoemission spectroscopy of an atomically thin semiconductor in the presence of a high-density of resonantly and coherently photoexcited excitons, we observe the Bardeen-Cooper-Schrieffer (BCS) excitonic state - analogous to the Cooper pairs of superconductivity. We see the valence band transform from a conventional paraboloid into a Mexican-hat like Bogoliubov dispersion - a hallmark of the excitonic insulator phase; and we observe the recently predicted giant exciton-driven Floquet effects. Our work realizes the promise that intense bosonic fields, other than photons, can also drive novel quantum phenomena and phases in materials.

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  1. Exciton photoemission from a ground state of a solid Ta2Pd3Te5

    cond-mat.str-el 2025-07 conditional novelty 6.0 of 10

    Photoemission evidence for spontaneously formed excitons below Tc in Ta2Pd3Te5, with an extracted Bohr radius of about 14 Å and an apparently odd-parity wave function.

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